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Primary segregations arises during the solidification of the steel, at
the transition of the phase from the liquid into the solid condition. There are to
distinguish ingot segregation and crystal segregation. Ingot segregations arises because
of a volume shrinkage at the solidification of a ingot. In front of the solidification
accompanying elements and inclusions are pushed and were enriched in the rest of the
cast. Crystal segregation are separations and arises at fast cooling, because then
there is remaining no time for the concentration compensation. Microscopic concentration
differences arises, because at solidification begin first such crystal precipitate
which are low at accompanying elements such as phosphorus, sulphur and carbon. Only
with a progressive solidification the amount of solidification share accumulates .
The content of alloying elements increases from inside to the outside at the crystallite.
Rest fields show the highest concentration in accompanying elements. The extent is
certainly of being struggled by the size of solidification interval, the diffusion
ability of the accompanying elements and the solidification conditions. Segregations
can be proved with the microsample, by making a pickle test, by etching of microsections
and by the making sulphur prints. Segregations impair a number of steel qualities.
The following links leads you to enlarged representations
of the segregation distribution at different steel grades. It is continuous casting
material which is rolled to round dimensions.
The magnification is, when not differently noted, 50:1
. The pictures have a additional magnification
on dem screen from ca. 40 % (refered on 17" screen at 1024 x 768 Pixel). If there is a modem connection you have to calculate longer times for loading,
because the represented pictures have shown a size of ca. 200 - 600 Kbyte. No stronger
compression of the photos could be carried to ensure an image quality as high as possible.
The pictures represent only a choice of possible crystalline structures and segregation
distributions at different heat treatment conditions. The segregation distribution
is dependent on different factors which positively or negatively influence the form.
This factors are casting temperature, casting rate, stirring parameter and cooling
rate.
Segregation structures at different materials
1.5510 - 28 B 2 spheroidised
11,50 mm

1.7225 - 42 CrMo 4 spheroidised
13,00 mm

1.1213 - Cf 53 spheroidised
14,50 mm

1.6582 - 34 CrNiMo 6 spheroidised
12,00 mm

1.2550 - 60 WCrV 7 spheroidised
13,00 mm

1.7034 - 34 Cr 4 spheroidised
11,00 mm

1.7076 - 32 CrB 4 spheroidised
13,00 mm

1.7220 - 34 CrMo 4 spheroidised
13,00 mm

1.7139 - 16 MnCrS 4 spheroidised
16,00 mm

1.7709 - 21 CrMoV 5-7 spheroidised
11,00 mm

1.2201 - X 165 CrV 12 spheroidised
15,00 mm

1.4718 - X 45 CrSi 9-3 spheroidised
16,50 mm

1.2344 - X 40 CrMoV 5-1 spheroidised
16,50 mm

1.6540 - 23 MnNiCrMo 5-3 spheroidised
13,50 mm

1.5523 - 19 MnB 4 spheroidised
11,50 mm

1.7039 - 41 CrS 4 spheroidised
15,50 mm

1.8159 - 50 CrV 4 spheroidised
13,50 mm

1.2510 - 100 MnCrW 4 spheroidised
16,00 mm

1.7160 - 16 MnCrB 5 spheroidised
22,00 mm

1.5920 - 18 CrNi 8 untreated
20,00 mm

1.8519 - 31 CrMoV 9 quenched
and tempered 13,50 mm

1.7131 - 16 MnCr 5 untreated
13,50 mm

1.6527 - 20 NiCrMo 3 spheroidised
6,50 mm

1.5919 - 15 CrNi 6 spheroidised
18,00 mm

1.7077 - 36 CrB 4 untreated
23,00 mm

1.5752 - 14 NiCr 14 stress
relief annealed 17,00 mm

1.7035 - 41 Cr 4 untreated
18,50 mm

1.2343 - X 38 CrMoV 5-1 spheroidised
18,00 mm

1.8507 - 34 CrAlMo 5 spheroidised
11,00 mm

1.6541 - 23 MnNiCrMo 5-2 spheroidised
14,00 mm

1.6546 - 40 NiCrMo 2-2 untreated
12,00 mm

1.2826 - 60 MnSiCr 4 spheroidised
13,00 mm

1.7102 - 54 SiCr 6 stress
relief annealed 15,00 mm

1.2103 - 58 SiCr 8 stress
relief annealed 14,00 mm

1.7147 - 20 MnCr 5 stress
relief annealed 20,00 mm

1.0570 - St 52-3 untreated
20,00 mm

1.2210 - 115CrV3 untreated
14,00 mm

1.5535 - 23MnB4 untreated
13,00 mm

1.2833 - 100V1 spheroidised
20,00 mm

1.5408 - 30MoB1 untreated
19,00 mm

Carbide distributions at different
materials
1.4037 - X 65 Cr 13 spheroidised
14,50 mm

1.2201 - X 165 CrV 12 spheroidised
15,00 mm

1.4116 - X 50 CrMoV 15 spheroidised
48,00 mm

1.3505 - 100 Cr 6 spheroidised
(quenched) 14,50 mm

1.2210 - 115 CrV 3 spheroidised
(quenched) 15,00 mm

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